Flash Point of petroleum products OilChat#18

In this issue of OilChat we will endeavour to clear some of the fallacies surrounding Flash Point. It is often believed that the Flash Point of a volatile liquid is the temperature at which the liquid will ignite (start to burn) spontaneously without an ignition source. This however is not true. Flash Point is defined as the lowest temperature at which a liquid (usually a petroleum product) will form a vapour in the air near its surface that will “flash, ” or briefly ignite, on exposure to an open flame.

Flash Point is an indication of the flammability or combustibility of a substance. The lower the Flash Point, the greater the fire hazard. The use of the Flash Point as a measure of the hazardousness of petroleum products dates back to the 1 9th century. Before the advent of automobiles, paraffin was the most sought after petroleum product which was primarily used as fuel for lamps and stoves. At the time there was a tendency by petroleum distillers to leave as much as possible of the commercially ‘worthless’ petrol in the paraffin in order to produce more product. This adulteration of paraffin with highly volatile petrol caused numerous fires and explosions in storage tanks and household appliances. In response legal measures were instituted to curb the danger, test methods were prescribed and minimum flash points were set.

You may well wonder why we sometimes find a variance when we compare the Flash Points of two similar products. The answer lies in the test method used. Flash points are measured by heating a liquid to specific temperatures under controlled conditions and then applying a flame to the vapour above the surface of the liquid. The test is done in either an “open cup” or a “closed cup” apparatus.

In the open cup test the sample is poured into a test cup that is completely open at the top. A thermometer is placed in the sample before it is heated. The test flame is passed over the cup at every 2 0 C increase in the sample temperature. When the sample vapours ignite momentarily the Flash Point is reached. The most commonly used test method is the ASTM D92 Cleveland Open Cup (COC) test.

In the case of the closed cup test, the sample is placed in a test cup with a sealed lid that opens when the ignition source (flame) is applied. The closed cup traps all the vapours that are generated during the heating of the sample and the vapours are not exposed to the atmosphere as they are in the open cup method. It is therefore no surprise that the closed cup test yields lower Flash Points than the open cup test. The ASTM D93 Pensky-Martens Closed Cup (PMCC) test is normally used to determine closed cup Flash Points. There is no set conversion factor for these Flash Point tests but PMCC is generally 5 0 C to 1 SC lower than COC for lubricating oils.

Flash Point is often used as a descriptive characteristic of petroleum products, and it is also used to help portray the fire hazards of liquids. It refers to both flammable and combustible liquids. There are various standards for defining each term but it is generally agreed that:

  • liquids with a PMCC Flash Point less than 37.8 0 C are flammable, and
  • liquids with a PMCC Flash Point higher than 37.8 0 C are combustible.

Although Flash Point primarily characterizes the fire hazards of liquids, it can also be an indicator of the quality of the base oils used in lubricants. In days gone by Flash Point was not really an issue but since the introduction of lower viscosity oils, such as SAE 5W-40 and even SAE OW-30, it became a more important consideration. The thinner the oil, the lower the Flash Point and the greater the tendency for the oil to suffer vapourisation loss at elevated temperatures. This results in the oil to burn off on hot cylinder walls and pistons in engines and thereby increasing oil consumption. A PMCC Flash Point of 2000 C is generally recognised as the minimum Flash Point for engine oil to prevent possible increased oil consumption at high operating temperatures.

If the open cup test is continued at increased temperatures after the Flash Point is attained, a point may be reached where the vapour continues to burn after being ignited. When the sample vapour sustains combustion, the Fire Point is reached. The Fire Point of a liquid can therefore be defined as the lowest temperature at which the vapour continues to burn (for at least five seconds) after being ignited by an open flame. The Fire Point for petroleum products is seldom listed, while Flash Point appears on most product data sheets. Generally, the Fire Point is about 1 O O C higher than the Flash Point, but if the value must be known, it should be determined experimentally. It should be noted that Fire Point testing is not undertaken in closed cup apparatus.

What many people perceive to be the Flash Point is actually the Auto-Ignition Temperature. Unlike with Flash Point and Fire Point, the Auto-Ignition Temperature does not need an ignition source. The Auto-Ignition Temperature of a substance is the lowest temperature at which it will ignite spontaneously in a normal atmosphere without an external source of ignition, such as a flame or spark. The Auto-Ignition Temperature (also known as Kindling Point) is a much higher temperature than the Flash Point and Fire Point.

Q8Oils and BCL sign lubricant agreement

Leading automotive, industrial and energy solutions manufacturer Q8Oils – a subsidiary of oil giant Kuwait Petroleum Corporation – has signed a distribution and manufacturing license agreement with South Africa-based Blue Chip Lubricants Pty Limited. Based in Randburg, Blue Chip’s role as sole importer and distributor of Q8 lubricants in South Africa will also see the company manufacture locally to ensure they can deliver a high level of service and flexibility to their customers.

Commenting for Blue Chip, director Gary Marais says: “All products manufactured locally will be blended under strict Q8Oils quality controls, using its own high-quality base oils and additives. In addition, the formulations we use are the same as those used by Q8Oils customers in Europe and North America.”

Established in 1983, Blue Chip Lubricants is a leading independent manufacturer, marketer and distributor of a wide variety of high-quality lubricants and greases in South Africa; and has gained a reputation for the production of reliable products and services.

Championing the partnership, Q8Oils regional sales manager Abdulmohsen Homoud says: “When choosing a partner for this region it was essential that we found a high-quality blender and a ‘can do’ partner, both technically and commercially. The Q8Oils and Blue Chip partnership is a perfect fit for the South African market, with customers being the ultimate winners.”

He goes on to say that, with Q8Oils’ marketing, manufacturing and research headquarters remaining in Europe, Blue Chip has significant corporate resources to call on whenever they are required.

Universal tractor lubricants OilChat#17

This is not an optical illusion.

Tractors don’t come up on our radar screens all that often but modern farm equipment is a far cry from the “mechanical plow horses” of yesteryear. These new machines may still not break any speed record, but space technology is now being incorporated into agricultural equipment in the form of GPS devices, onboard computers, auto-steer system and even driverless technology!

Notwithstanding this array of state-of-the-art gizmos, lubrication still plays a critical role in the efficient and reliable operation of agricultural machinery. Tractors and other farm equipment, such as combined harvesters, have various components that need to be lubricated. These include the engine, transmission, final drives, oil immersed ( wet ) brakes hydraulic system and the power take-off ( PTO ). Just imagine the cost consequences if farmers had to stock different oils for all these applications. Furthermore, with so many lubricants in the oil store, there is also the risk of using the wrong oil for a specific component. It is therefore no wonder that agricultural equipment manufacturers and oil companies have worked together to come up with multifunctional lubricants:

Super Tractor Oil Universal (STOU/SUTO)

These oils fulfill several roles and make machine maintenance much simpler. They also reduce the number of lubricants farmers need to keep around because they can generally be used for all the applications mentioned above. When you peruse the product data sheet of a reputable STOU you will find that it meets the requirements of a host of Industry and Equipment Manufacturers’ (OEM) specifications. These may include, but are not limited to, the following:

  • Engines: API CG-4/SF
  • Gears: AP GL-4
  • Transmissions: ZF TE-ML 06A / 06B / 06C / 06G
  • Wet Brakes: Case MS 1317
  • Hydraulics: Eaton Vickers M-2950-S.

A STOU fluid can be described as a general-purpose farm lubricant with reasonable engine performance, fair load carrying capacity for gears and moderate hydraulic oil performance. However, as engines become more demanding, transmissions more sophisticated and hydraulic system pressures higher, trying to meet all the requirements with one fluid becomes more complicated. For instance, if a manufacturer recommends an API CI-4 performance level oil for the engine, two separate lubricants may have to be used since it is unrealistic to expect a single oil to meet API CI-4 and all the other service categories mentioned above. In such an instance it would be advisable to use a dedicated engine oil and a higher performance multifunctional lubricant for the other components.

Universal Tractor Transmission Oil ( UTTO )

These lubricants are also referred to as Tractor Hydraulic Fluid ( THF ) or Transmission, Differential and Hydraulic ( TDH ) fluid. They are used where the equipment manufacturer recommends a separate engine oil. UTTOshave no engine oil credentials, better hydraulic oil performance and improved wet brake fluid characteristics.

When you compare STOU and UTTO product data sheets you may well find they have some transmission, rear axle, wet brake and hydraulic oil specifications in common. However high-performance UTTOs will boast with OEM specifications that are unlikely to be met by STOUs such as:

  • Case MS 1207: Hy-Tran Plus, transmissions, hydraulics, wet brakes
  • Massey Ferguson CMS M 1141: Transmissions, hydraulics, highly loaded wet brakes
  • Volvo 97302-10: Transmission with built in wet brakes

As tractors become more sophisticated and require higher quality oils for satisfactory performance, there will most likely be an increased trend away from the all-purpose STOU fluid to a specific engine oil and UTTO combination.

TO-4 Fluid

UTTOs should not be confused with TO-4 fluids. UTTOs are mainly used in agricultural applications, although they are sometimes recommended for construction machines, such as Bell ATDs. TO-4 fluid originates from the Caterpillar TO-4 ‘Transmission Oil’ specification. TO-4 has become a standard term used within the industry for a specific type of additive/ fluid. TO-4 fluids normally meet Allison C4and other OEMrequirements as well.

Although both UTTOs and TO-4 fluids are designed for wet brake applications, they are not interchangeable since they have different frictional properties.Construction machinery, for which TO-4 fluids are intended, is normally much bigger and heavier than agricultural equipment. A higher level of friction is required to ensure that these heavy machines can stop on steep slopes, such as access roads down open cast mines.Tractor size, and therefore weight, is limited, as they need to use public roads, and therefore less friction is required to stop agricultural equipment. This results in TO-4 fluids having a higher coefficient of friction than UTTOs. Using the wrong fluid will mean that fluid/brake surface interaction will be affected and thereby reducing braking efficiency with possible catastrophic results.

Conclusion

Know your equipment manufacturer’s recommended lubricants, have them on hand and pay attention to tractor and equipment service intervals. If in doubt our experts are at your disposal, ready to provide you with advice and to answer any of your questions. For more information, please visit www.bcl.q8oils.co.za

Lubricating grease part 2 OilChat#16

Grease consists of a liquid lubricant that is mixed with a thickener ( see OilChat #15 ). Additives imparting special properties may also be included. Although is is liquid lubricant ( and certain additives) in the grease that provides the necessary lubrication, grease and oil are not interchangeable in their applications. The combination of the thickener, fluid and additives incorporated in grease produce certain properties or characteristics that grease does not share with lubricating oil.

The characteristics most commonly considered when selecting grease for a specific application included, but are not limited to the following:

Consistency is a key property of grease and is a measure of the relative hardness of the grease. Consistency is measured using a “penetrometer”. A cone is released and allowed to sink into the grease, under its own weight, for 5 seconds. The depth that the cone has penetrated into the grease is then read in tenths of a millimeter. The further the cone penetrates the grease, the higher the penetration result and the softer the grease. The National Lubricating Grease Institute (NLGI) has established consistency numbers ranging from 000 to 6, corresponding to specified ranges of penetration numbers. The table below lists the NLGI grease classifications along with a description of the consistency and how it relates to common foods:

NLGI 2 grease is the most common consistency used globally

Dropping Point is indicative of the heat resistance of grease. The Dropping Point is the temperature at which grease becomes fluid enough to drip under controlled conditions in a laboratory test. In general, the dropping point is the temperature at which the grease passes from a semisolid to a liquid state. This change is irreversible in greases containing conventional soap thickeners. Greases with materials other than conventional soap thickeners can, without a change in state, separate oil. The dropping point indicates the upper-temperature limit at which a grease retains its structure and NOT the maximum temperature at which a grease may be used. A good rule of thumb is to consider the dropping point minus 50°C as the maximum useful temperature limit.

Oxidation Stability is the ability of grease to resist breakdown in reaction with oxygen at elevated temperatures. Although both the base oil and thickener can oxidize, oxidation is more of a danger to the base oil. Oxidation turns grease into a sludge and causes gummy deposits to form on machine and component surfaces. Oxidized grease will become softer and appear darker. Prolonged exposure to excessive temperatures accelerates oxidation and can even result in carbonization where grease hardens or forms an abrasive black crust.

Structural Stability is a vital performance characteristic of lubricating grease as it is a measure of how the grease consistency will change in service when it is subjected to shear as a result of movement. Grease softening in a bearing may cause the grease are developed through careful selection of the thickness composition and effective manufacturing process.

Water Resistance is the ability of grease ti withstand the effects of water with no or little change in its ability to lubricate. Water can affect the grease stability resulting in hardening of softening. A drop inconsistency can cause the grease to be washed away from the bearing. In some instances, grease may also absorb the water and suspend the oil in the grease forming an emulsion that can reduce lubricity by diluting and changing grease consistency and texture. In extreme case water can displace the oil completely, causing the oil to leak away. In order to maintain its structure, the grease is required t have good water repellence in addition to adequate water tolerance properties.

Pumpability is an indication of how easily pressurized grease will flow through lines, nozzles, and fitting of grease dispensing system. Good pump ability characteristics are particularly important at low operating temperatures or when grease is used in automatic lubrication system where the grease is pumped through long lines from a central reservoir. If the temperature of grease is lowered sufficiently, It will become to viscous to flow and machine operation will be impossible. It is therefore important to check the recommended usable temperature range on the product data sheet when considering grease for arduous climatic condition.

Load Carrying Capacity is defined by the American Society for Testing and Material ( ASTM ) as the maximum load or pressure that can be sustained by a lubricating grease without failure of the sliding contact surfaces. In some circumstances the lubricating oil in the grease will prevent the breakdown of the lubricating fluid film under load, and only the action of anti-wear or extreme pressure (EP) additives in the grease will prevent surface contact and wear. in test to evaluate the load carrying capacty of grease, high loads are applied to moving surfaces that are in contact and lubricated by the grease. There are many test for determining the load carrying ability of grease, but the most commonly used ones are the Timken OK Load test and the Four Ball Weld/ Load Wear Index test.

When selecting grease fo a particular application all of these properties need to be compared to the requirenebts of the application. It could be disastrous to choose a grease based on NLGI grade only. The completed package of grease characteristics, including the fluid component viscosity, must be considered in order to choose the best grease for the job.

Important to remember is that all grease are not compatibile. It is therefore recommended that when changing from one grease to another, all the old grease should be cleaned out before the new grease is applied.